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A New Approach to the Ring Opening Reactions of 2,7,7-Trimethyl-3,3-dibromotricyclo[4.1.1.02,4]octane
2,7,7-Trimethyl-3 3-dibromotricyclo[4.1.1.02,4]octane
2010/4/20
The reaction of a-pinene and dibromocarbene produced a fairly unstable product, 2,7,7-trimethyl-3,3-dibromotricyclo[4.1.1.02,4]octane, from which 3-bromo-7,7-dimethyl-2-methylenebicyclo[4,1,1]oct-3-en...
The Hydrodynamic Properties of Micelles Formed by Block Copolymers of Isoprene and tert-Butylacrylate in n-Octane
Block copolymers hydrodynamic properties micellisation
2010/4/20
The hydrodynamic properties of micelles formed by 2 block copolymers of isoprene and tert-butylacrylate in n-octane were investigated by dynamic light scattering (DLS) over a range of temperatures and...
An Investigation of the Formation Mechanism of Allene or Alkyne in the 6,7-Benzobicyclo[3.2.1]octane System by Deuterium Labeling Experiments
Cyclic allene Cyclic alkynes Deuterium Labeling
2010/6/28
In order to reveal the real intermediate in the base-promoted reaction of 1, 3-bromo-4,4-dideuterio-6,7-benzobicyclo[3.2.1]octa-2,6-diene 10 was synthesized and its HBr elimination reaction studied. R...
Structure of A 1,4-Diazabicyclo[2,2,2]Octane-Vermiculite Intercalate
Crystal structure DABCO Intercalate Stacking ordering Vermiculite
2011/11/30
Abstract: 1-4-diazabicyclo[2,2,2]octane dihydrochloride (DABCO·2HCl) was reacted with two vermiculite samples to produce intercalates which, at room temperature, had relatively sharp, single crystal X...
Surface Properties of Smectites Exchanged with Mono- and Biprotonated 1,4-Diazobicyclo(2,2,2)-Octane
Dabco Interlayering Pillar Smectite Surface area
2012/2/7
Smectites exchanged to various degrees with mono- or biprotonated 1,4-diazobicyclo(2,2,2)- octane (Dabco) have a porous structure in which the organic molecule acts as a 乬pillar.乭 Less Dabco2+ than Da...