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Abstract: Self-diffusion coefficients of H2O molecules in Na-rich hectorite gel were measured by 1H nuclear magnetic resonance (NMR). Spin-echo pulse sequences with magnetic field gradient pulses for ...
Abstract: Adsorptive-type organoclays, where hydrocarbons adsorb directly to the siloxane surfaces, were studied to find new organic cations and to determine the parameters that produce effective sorb...
The technique of scanning force microscopy (SFM) was used to study the nanometer-scale structure of Cu(II)-exchanged hectorite thin films. Supporting data were also obtained from Electron Spin Resonan...
Electron spin resonance (ESR) spectroscopy was used to measure the rotational mobility of an uncharged nitroxide spin probe (4-hydroxy-2,2,6,6-tetramethyl-piperidinyloxy) in hectorite gels of variable...
Abstract: The safe disposal of 60Co, 63Ni, and 59Ni has required considerable information on the interactions of Co2+ and Ni2+ with clay minerals in the geosphere. X-ray photoelectron spectroscopy (XP...
The Derjaguin-Landau-Verwey-Overbeek (DLVO) theory sums the attractive van der Waals and repulsive electrostatic forces as a function of separation distance to predict the interaction between charged ...
The absorption spectra of methylene blue ion exchanged on hectorite, Laponite B, Barasym, or sepiolite in dilute aqueous suspensions show the presence of the monomer, the protonated monomer, the dimer...
Copper adsorption on a hydroxy-aluminum-hectorite complex (OH-Al-hectorite) at pH 4.5, 5.7, 7.4, and 7.8 was examined by means of electron spin resonance. The spectra of these samples were compared to...
The exchange of Rh(NBD)(Pφ3)2+, Rh(NBD)(PMe2φ)3+, Rh(COD)(Pφ3)2+, and Rh(PMe2φ)4+ on hectorite was studied in methanol/dichloromethane, acetone, dimethylformamide, and acetonitrile. At low initial Rh+...
The hydrolysis and decomposition of M-hectorite (M being Na, Li, Mg, or Ca) in dilute solutions of M-chlorides were studied by recording the changes in electrical conductivity (EC) of the clay suspens...
Electron spin resonance (ESR) analysis of Cu2+-hectorite suspensions provides evidence for the surface-induced hydrolysis of Cu(H2O)62+ at low pH and surface-inhibited hydrolysis (or precipitation) at...
Silica-intercalated hectorite with an 001 spacing of 12.6 侌 and a N2 BET surface area of 220 m2/ g was prepared by hydrolysis and oxidation at 500亱C of hectorite containing a silicon acetylacetonate c...
Proton Nuclear Magnetic Resonance Studies of “One-Layer” Hydrates of Oriented Hectorite.
The adsorption of Sn(IV)TPyP (mesotetrapyridylporphyrin) in sodium hectorite was studied using ultraviolet-visible and luminescence spectroscopy. The adsorbed complex was found to demetallate forming ...
The nature of the complexes in aqueous solutions of Cu(II) and Ni(II) with diethylenetriamine (dien) and tetraethylenepentamine tetren) is pH-dependent. At M(II):dien = 2 and M(II):tetren = 1, the mai...

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