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The Role of the Distal and Proximal Protein Environments in Controlling the Ferric Spin State and in Stabilizing Thiolate Ligation in Heme Systems:Thiolate Adducts of the Myoglobin H93G Cavity Mutant
salicylic alcohols hydrogen bonds quantum chemistry
2016/5/23
Recently, heme protein cavity mutants have been engineered in which the proximal coordinating amino acid has been replaced by a smaller, noncoordinating residue leaving a cavity that can be filled by ...
Distance Dependence of Electron-Transfer Reactions in Organized Systems:The Role of Superexchange and Non-Condon Effects in Photosynthetic Reaction Centers
Distance Dependence Electron-Transfer Reactions Organized Systems Superexchange Non-Condon Photosynthetic Reaction Centers
2016/5/23
Extremely long distance electron transfer is observed in some photosynthetic reaction centers. For several charge recombination reactions, the rate appears to fall off much more slowly with distance t...
Hydrogen storage via physisorption: the combined role of adsorption enthalpy and entropy
Adsorption thermodynamics enthalpy-entropy correlation hydrogen physisorption hydrogen storage
2010/4/8
Materials capable of cost-effective on-board hydrogen storage and delivery are currently being sought worldwide as a means to facilitate a hydrogen-based energy transition in the transportation sector...